To my knowledge, the following was the first publication on successful VLBI observation:
Broten N.W., Legg T.H., Locke J.L., McLeish C.W., Richards R.S., Chisholm R.M., Gush H.P., Yen J.L., Galt J.A. Long Base Line Interferometry: A New Technique. Science, 1967, v.~156, No.~3782, 1592--1593. received: 28.03.1967, published: 06.1967
It was the Algopark - DRAO baseline, as I remember.
Regards,
Zinovy